Berichtigung: Mediated Inner‐Sphere Electron Transfer Induces Homogeneous Reduction of CO ₂ via Through‐Space Electronic Conjugation

It has come to the authors attention that experimental turnover frequencies (TOFs) were calculated incorrectly by using a second-order rate constant for reaction instead of first-order observed as defined in original derivation.1, 2 The presented TOF values from re-analyzed electrolysis data are shown below an updated version Table 1. These should replace those originally published 1 and also their mention discussion Abstract text. Conditions Potential (V vs. Fc+/Fc) FECO [%] TOFCPE [s–1] η [V] TONCO (w.r.t [1]) [DBTD]) [Cr] −2.3 0 – DBTD 32±1 0.90 [Cr]+DBTD 91±10 36.8 0.69 16 3.1 DBTD+PhOH 28±1 0.52 + PhOH 111±14 7.12 0.11 11.4 [Cr]+ PhOH+DBTD 102±14 65.3 0.41 29 5.8 −2.7 57±3 1.14 0.81 [Cr]+PhOH[a] −2.1 96±8 4.35 15[a] corrections do not affect primary conclusions mechanistic analysis Communication. However, any comparison other previously reported systems no longer applies. Consistent with this, revised Supporting Information document now shows correct derivation TOFs data, well catalytic Tafel Plot Figure S35.